Practical synthesis of 1,5-dimethyl substituted conjugated polyenes from geranyl acetate |
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| Authors: | Yu-Jun Zhao |
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| Affiliation: | Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore |
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| Abstract: | A protocol to synthesize 1,5-dimethyl substituted conjugated polyenes via dehydrogenation of geranyl acetate was established. C5 unit elongation to multi-1,5-dimethyl substituted conjugated polyenes was also achieved via Horner-Wadsworth-Emmons olefination in good yields and good selectivities. |
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| Keywords: | Elimination Olefination Conjugated Terpenoids Natural Products |
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