Structure-activity relationship study of flowering-inducer FN against Lemna paucicostata |
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Authors: | Kenji Kai Jun Takeuchi Mineyuki Yokoyama |
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Institution: | a Graduate School of Science and Technology, Shizuoka University, 836, Ohya, Suruga-ku, Shizuoka 422-8529, Japan b Faculty of Agriculture, Shizuoka University, 836, Ohya, Suruga-ku, Shizuoka 422-8529, Japan c H&BC Research Center, Shiseido Co. Ltd, 2-12-1, Fukuura, Kanaza-ku, Yokohama 236-8643, Japan |
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Abstract: | FN1 (1) and FN2 (2), cycloadducts of α-ketol octadecadienoic acid (3) with norepinephrine (NE), induce flowering in Lemna paucicostata. In order to broaden our understanding of structural requirements of FN for flower induction, nine analogs of 3 (4-12) were synthesized and reacted with NE under basic conditions. These analogs, except for 8, 10, and 12, exhibited significant activity regarding to floral induction in L. paucicostata. Similar experiments were carried out by using 3 and epinephrine, and it was demonstrated that these products also possessed biological activity. |
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Keywords: | Lemna paucicostata Flowering FN Oxylipins Analog Structure-activity relationship |
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