Reactivity of Ph3PNLi towards P and P electrophiles |
| |
Authors: | Nicolas J. Rahier |
| |
Affiliation: | Institut Charles Gerhardt Montpellier, CNRS UMR 5253 (AM2N), Ecole Nationale Supérieure de Chimie de Montpellier, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France |
| |
Abstract: | A study of the reactivity of Ph3PNLi towards phosphorus electrophiles allowed us to develop a general method to isolate, or cleanly generate in situ, a broad family of polyphosphinimines displaying PN-P bonds. A preliminary application of this methodology is presented here with the synthesis of various Schwesinger-type bases by a simple new procedure employing Ph3PNLi. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|