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Synthesis,GC-EIMS,~1H NMR,~(13)C NMR,Mechanistic and Thermal Studies of o-Xylylene-α,α'-bis (triphenylphosphinebromide)
作者姓名:Muddasir  Hanif
作者单位:Supramolecular;Structure;Materials;Jilin;University;
基金项目:Supported by the National Natural Science Foundation of China(Nos.20573040,20474024,20125421,90101026 and 50303007)
摘    要:Organophosphorous compounds containing phosphorus as an integral part have been widely used in industry, organic synthesis and optoelectronics. o-Xylylene-α,α'-bis(triphenylphosphinebromide)(OXBTPPB) is a facile reagent to convert o-quinones(e.g., 9,10-phenanthrenequinone) into polycyclic aromatic hydrocarbons(PAHs). Herein lies an improved synthetic route to OXBTPPB. The resultant was carefully characterized with GC-EIMS, 1H NMR, 13C NMR, spectroscopic techniques. The EIMS shows characteristic peaks at m/z...


Synthesis, GC-EIMS, 1H NMR, 13C NMR, Mechanistic and Thermal Studies of o-Xylylene-α,α'-bis(triphenylphosphinebromide)
Muddasir Hanif.Synthesis, GC-EIMS, 1H NMR, 13C NMR, Mechanistic and Thermal Studies of o-Xylylene-α,α''-bis(triphenylphosphinebromide)[J].Chemical Research in Chinese University,2009,25(5).
Authors:Muddasir Hanif  MA Yu-guang  LU Ping  XU Hai  TIAN Zhi-cheng  YANG Bing  WANG Zhi-ming  TIAN Lei-lei  XU Yuan-ze  XIE Zeng-qi
Abstract:
Keywords:Organophosphorous compound  o-Quinone  Molecular structure  Optoelectronics  
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