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Regioselective organocadmium alkylations of substituted quinones. |
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| Authors: | Aaron Aponick Ryan S Buzdygon Robert J Tomko Aleem N Fazal Ellen L Shughart Danielle M McMaster Michael C Myers William H Pitcock Carl T Wigal |
| Affiliation: | Department of Chemistry, Lebanon Valley College, Annville, Pennsylvania 17003, USA. |
| Abstract: | A series of substituted quinones was alkylated with diethylcadmium. Regiochemistry of addition shifted from quinol formation to conjugate addition as a function of the steric and electronic effects of the substituents. |
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