Remarkable selectivity in addition of alcohols to epoxydienes of 5,7 bicyclic and 5,7,6 tricyclic systems |
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| Authors: | Boyer François-Didier Hanna Issam |
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| Institution: | Unité de Phytopharmacie et Médiateurs Chimiques, INRA, Versailles, France. |
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| Abstract: | Acid-catalyzed addition of alcohols to tricyclic dienyl epoxides such as 4 or bicyclic vinyl oxiranes such as 17 exclusively occurred at the vinyl terminus of unsaturated system through a typical S(N)2' process affording 1,6- and 1,4-dioxygenated derivatives, respectively. |
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