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CONCENTRATION EFFECT OF SENSITIZING DYE ON SPECTRAL SENSITIZATION OF SILVER HALIDE
作者姓名:李宝芳  李津如  江龙
作者单位:Institute of Photographic Chemistry,Academia Sinica,Beijing,Institute of Photographic Chemistry,Academia Sinica,Beijing,Institute of Photographic Chemistry,Academia Sinica,Beijing
摘    要:The effect of concentration of four dyes has been investigated, which are of similar mo-lecular structures, same spectroscopic absorption spectra, and very close values in redox po-tential upon the spectral sensitization of photographic emulsion. The results have shownthat dyes which are liable to form J-aggregate diminish the effect of dye-induced desensiti-zation, while dyes which are not easy to form J-aggregate exhibit a very strong effect ofdye-induced desensitization. According to phosphorescence and electrochemistry experimentalresults, we could assume that the aggregate state acts in a way to regenerate the oxidizeddye, thus being favorable to the spectral sensitization. In this paper, the factor of inhibi-tion of development by dye adsorption has also been proposed to be a factor which cannotbe neglected in dye-induced desensitization.

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