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以对甲基苯磺酸作为淋洗液用离子色谱法测定酸雨中的有机酸
引用本文:俞绍才,栗欣,毕木天.以对甲基苯磺酸作为淋洗液用离子色谱法测定酸雨中的有机酸[J].分析化学,1991(1).
作者姓名:俞绍才  栗欣  毕木天
作者单位:北京大学技术物理系,北京大学技术物理系,北京大学技术物理系 毕业研究生 北京 100871,厦门环保所,北京 100871,北京 100871
摘    要:本文研究了用对甲基苯磺酸作为淋洗液测定液相中HCOO~-和CH_3COO~-的离子色谱条件,该方法对HCOO~-和CH_3COO~-的最低检出限分别为48ppb和93ppb。该方法与用进口的辛磺酸作为淋洗液的方法进行了对比实验,并用于两广实际酸雨样品中甲酸和乙酸的测量。

关 键 词:对甲基苯磺酸  离子色谱  有机酸  酸雨

Determination of Organic Acid in Acid Rain by lon Chromatography With p-Toluene Sulfonic Acid as Eluant
Yu Shaocai,Li Xin,Bi Mutian.Determination of Organic Acid in Acid Rain by lon Chromatography With p-Toluene Sulfonic Acid as Eluant[J].Chinese Journal of Analytical Chemistry,1991(1).
Authors:Yu Shaocai  Li Xin  Bi Mutian
Institution:Yu Shaocai~*,Li Xin,Bi Mutian
Abstract:The conditions of ion chromatography using p-toluene sulfonic acid as eluant for the determinaion of HCOO~- and CH_3COO~- in acid rain were studied. The minumum detectable concentrations of HCOO~- and CH_3COO~- were about 48 ppb and 93 ppb respectively. Experiments compared with ion chromatography method using octane sulfonic acid as eluant were described, and this method was used to measure formic and acetic acids in acid rain at Guangdong and Guangxi province.
Keywords:p-Toluene sulfonic acid  Ion chromatography  Formic acid  Acetic acid  Acid rain
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