Condensed Tetrazolo-1,3,5-triazines. 2. Alkylation and Nucleophilic Substitution of 5-Trinitromethyltetrazolo[1,5-<Emphasis Type="Italic">a</Emphasis>]-1,3,5-triazin-7-ones |
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| Authors: | B S Fedorov A N Utienyshev A A Ghidaspov E V Kachanovskaya V V Bakharev M A Fadeev |
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| Institution: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russia;(2) Samara State Technical University, 443010 Samara, Russia |
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| Abstract: | A new heterocyclic compound, 3-methyl-5-trinitromethyltetrazolo1,5-a]-1,3,5-triazin-7-one, was synthesized by the reaction of methyl iodide and the silver salt of 5-trinitromethyltetrazolo1,5-a]-1,3,5-triazin-7-one. An X-ray diffraction structural analysis of this product was carried out and feasibility was demonstrated for the nucleophilic substitution of the trinitromethyl group in this compound by the action of phenol, phenol derivatives, and thiophenol.__________Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 582–588, April, 2005. |
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| Keywords: | condensed tetrazolo-1 3 5-triazines 5-aryloxy-3-methyl- and 5-arylthio-3-methyltetrazolo[1 5-a]-1 3 5-triazin-7-ones 3-methyl-5-trinitromethyltetrazolo[1 5-a]-1 3 5-triazin-7-one alkylation nucleophilic substitution of the trinitromethyl group |
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