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The preparation and X-ray crystal structure of W3(μCN)3(NO)3(CO)9 |
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| Authors: | Helen M Dawes Michael B Hursthouse Alan A Del Paggio Earl L Muetterties Adrian W Parkins |
| Institution: | Chemistry Department, Queen Mary College, Mile End Road, London E1 4NS, U.K.;Chemistry Department, University of California, Berkeley, CA 94720, U.S.A.;Chemistry Department, Queen Elizabeth College, Campden Hill Road, London W8 7AH, U.K. |
| Abstract: | The nitrosation of NaW(CO)5CN] using amyl nitrite and sulphuric acid in a two phase water— diethyl ether system gives the trinuclear compound W3(μCN)3(NO)3(CO)9. A single crystal X-ray diffraction study showed that the compound contains a nine-membered ring of three tungsten atoms and three bridging cyanide groups. The terminal carbonyl and nitrosyl ligands were not distinguishable. |
| Keywords: | Author to whom correspondence should be addressed |
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