The crystal and molecular structure of Rh2(CH3CO2)4[HCON(CH3)]2—effect of ligands on metalmetal bonding |
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| Authors: | Monika Moszner Tadeusz Głowiak Józef J Ziółowski |
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| Institution: | Institute of Chemistry, University of Wroc?aw, 50-383 Wroc?aw, Poland |
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| Abstract: | The structure of Rh2(CH3CO2)4(DMF)2 {DMF = HCON(CH3)2} has been determined by single crystal X-ray methods. The compound crystallizes with eight formula units in a cell of dimensions: a = 29.438(7) Å, b = 7.978(2) Å, c = 20.279(5) Å, β = 113.20(4)°, V = 4377.5 Å3, space group C2/c. The structure has been refined by full-matrix least-squares method to a final R = 0.030 for the 4156 observed data. Two Rh(II) atoms are linked by four acetate groups forming a dimeric unit, where the RhRh distance is 2.383(1) Å. The coordination sphere about each Rh atom is completed by a DMF molecule; the average RhO(DMF) distance is 2.296(3) Å. |
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| Keywords: | Author to whom correspondence should be addressed |
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