N-methyl-2,2′-bipyridylium ion (bpyMe) complexes: Synthesis and cyclometallation of [Pd(bpyMe)2Cl2]2+ |
| |
| Authors: | Franz L Wimmer Smita Wimmer |
| |
| Institution: | School of Natural Resources, University of the South Pacific, Suva, Fiji |
| |
| Abstract: | On prolonged heating in water Pd(bpyMe)Cl3 (bpyMe = N-methyl-2,2′-bipyridylium cation) cyclometallates to give monomeric Pd(bpyMe-H)Cl2, whereas the immediate products are a mixture of trans-Pd(bpyMe)2Cl2]2+ and anionic palladium species. Pd(bpyMe)2Cl2]2+ was synthesised directly from Na2PdCl4 and on heating gives Pd(bpyMe-H)Cl2 with the elimination of bpyMe and H+. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
