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Effect of the substituents on the enantiomerization barrier energy of N-isopropylsalicylaldiminate beryllium and zinc complexes
Authors:FA Bottino  P Finocchiaro
Institution:Institute of Chemistry, Faculty of Engineering of the University, viale A. Doria 6, 95125 Catania, Italy
Abstract:Substituted bis-(N-isopropylsalicylaldiminate) complexes of Be(II) and Zn(II) have been prepared and their variable-temperature 1H NMR spectra have been investigated. The variation of the ΔG values for the enantiomerization process in these complexes was studied as a function of the substituents present in the aromatic ring.
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