Effect of the substituents on the enantiomerization barrier energy of N-isopropylsalicylaldiminate beryllium and zinc complexes |
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Authors: | FA Bottino P Finocchiaro |
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Institution: | Institute of Chemistry, Faculty of Engineering of the University, viale A. Doria 6, 95125 Catania, Italy |
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Abstract: | Substituted bis-(N-isopropylsalicylaldiminate) complexes of Be(II) and Zn(II) have been prepared and their variable-temperature 1H NMR spectra have been investigated. The variation of the ΔG≠ values for the enantiomerization process in these complexes was studied as a function of the substituents present in the aromatic ring. |
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Keywords: | Author to whom correspondence should be addressed |
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