Thiosemicarbazide complexes of antimony(III) halides |
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Authors: | J Masłowska K Oprza̧dek |
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Institution: | Institute of General Food Chemistry, Technical University of ?ód?, ul. Stefanowskiego 4/10, 90-924 ?ód?, Poland;Pedagogical Academy, Siedlce, Poland |
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Abstract: | Some hitherto unknown complexes of thiosermicarbazide (Htsc) and antimony(III) halides have been synthesized in 1,4-dioxane. The elemental analyses have indicated that these compounds are of the type Sb(CH5N3S)Cl3 and Sb(CH5N3S)X3.C4H8O2, where X = Br or I. The electronic and vibration spectral analyses have shown that Htsc acts as a bidentate ligand in these complexes, linking through sulphur and “the hydrazine terminal nitrogen” to Sb(III). |
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Keywords: | Author to whom correspondence should be addressed |
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