Polarographic study of Eu(III)-succinate-ethylenediamine and Eu(III)-malonate-ethylenediamine mixed systems |
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Authors: | Madhu Shivhare Mukhtar Singh |
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Affiliation: | Chemistry Department, Agra College, Agra 282002, India |
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Abstract: | The mixed complexes of Eu(III) with succinate (succ2?) and malonate (mal2?) and ethylenediamine (en) have been studied polarographically at 25°C and at constant ionic strength, μ = 0.1 (NaNO3) and pH 6. The reduction of the complexes in each case is quasi-reversible and diffusion-controlled. In each system three mixed complexes are formed, viz. [Eu(succ)(en)]+, [Eu(succ)(en)2]+ and [Eu(succ)2(en)]? with stability constants log β11 = 9.2, log β12 = 17.5 and log β21 = 11.7; and [Eu(mal)(en)]+, [Eu(mal)2(en)2]? and [Eu(mal)3(en)]3? with stability constants log β11 = 11.4, log β22 = 19.08 and log β31 = 13.5 respectively. |
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Keywords: | Author to whom correspondence should be addressed. |
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