Azides of heavier main group elements: The reluctance of phosphine azides to undergo a curtius-type rearrangement |
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| Authors: | Edgar Ocando Samia Majid Jean Pierre Majoral Antoine Baceiredo Guy Bertrand |
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| Affiliation: | U.A. 454, Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse, France;U.A. 477, Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse, France |
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| Abstract: | Under thermolytic or photolytic conditions, phosphine azide complexes Ph2PN3M(CO)5 (M = W, Cr) gave rise to the corresponding isocyanato complexes and not to the expected iminophosphane complexes. |
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| Keywords: | Author to whom correspondence should be addressed. |
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