Formation equilibria of copper(II) complexes with some pyridinols in various solvents |
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Authors: | R. Bucci V. Carunchio A.M. Girelli A. Messina |
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Affiliation: | Dipartimento di Chimica, Università degli Studi “La Sapienza”, P. le Aldo Moro 5, 00185 Roma, Italy |
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Abstract: | Complexation of copper(II) with two different pyridinols in three solvents has been studied by visible spectrophotometry and flow-microcalorimetry. The influence of the solvent on tautomeric equilibrium of the ligand, on distribution, on stability and on formation enthalpies of the main complex species is discussed. |
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Keywords: | Author to whom correspondence should be addressed. |
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