The structure of (dichloro) (DI-μ-acetato)(bis-triphenyl phosphine) dimolybdenum(II)期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

按检索

The structure of (dichloro) (DI-μ-acetato)(bis-triphenyl phosphine) dimolybdenum(II)

Authors:	FAlbert Cotton Gregory L Powell

Institution:	Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A & M University, College Station, TX 77843, U.S.A.

Abstract:	The title compound was obtained in crystalline form suitable for X-ray structure determination. It forms crystals in the monoclinic space group P2₁/c with two centrosymmetric molecules in a unit cell of dimensions, a = 10.888(1) Å, b = 10.182(2) Å, c = 17.929(4) Å, β = 104.33(1)°. The central Mo₂Cl₂(O₂C)₂P₂ core has effectively C_2h-symmetry with the following principal dimensions: MoMo = 2.091(1) Å, MoCl = 2.405 Å, MoP = 2.566(2) Å, MoO(av.) = 2.1034] Å, MoMoP = 104.38(7)°, and MoMoCl = 116.23(8)°.

Keywords:	Author to whom correspondence should be addressed
本文献已被 ScienceDirect 等数据库收录！