The direct electrochemical synthesis and crystal structure of salts of [M4(SC6H5)10]2? anions (M = Zn,Cd) |
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| Authors: | JLawrence Hencher Masood A Khan Farouq F Said Dennis G Tuck |
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| Institution: | Department of Chemistry, University of Windsor, Windsor, Ontario, Canada N9B 3P4 |
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| Abstract: | The salts (C2H5)3NH]2M4(SC6H5)10] (M = Zn, Cd) can be prepared by the electrochemical oxidation of the metal in an acetonitrile solution of triethylamine and benzenethiol. An X-ray crystal structure determination shows that the anion consists of a tetrahedron of metal atoms, each carrying a terminal -SC6H5 ligand, and connected to the three other metal atoms by bridging > SC6H5 groups. The results are compared with those for similar compounds reported in the literature. |
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| Keywords: | Author to whom correspondence should be addressed |
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