Optical activity of compounds formed by aminocomplexes of Co(III) and carbohydrates—I |
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| Authors: | S. Bunel C. Ibarra |
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| Affiliation: | Departamento de Análisis Químico, Facultad de Ciencias Básicas y Farmacéuticas, Universidad de Chile, Casilla 233, Santiago, Chile |
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| Abstract: | The preparation of aminocomplexes of Co(III) containing d-ribose, l-sorbose or d-glucosamine as second ligand is described. Their spectral features and optical activity are reported. Formation in solution of complex species with other chosen carbohydrates gives ground for discussion as to the origin and sign of the observed Cotton effects. |
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| Keywords: | Author to whom correspondence should be addressed. |
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