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Reaction of 4-Amino-3-methylthio-5-oxo-6-R-4,5-dihydro-1,2,4-triazines with Sulfonylacetic Acid Nitriles
Authors:V. N. Britsun  I. M. Bazavova  A. N. Esipenko  M. O. Lozinskii
Affiliation:(1) Ukraine National Academy of Sciences, Institute of Organic Chemistry, Kiev, 02094
Abstract:The reactions of 4-amino-3-methylthio-5-oxo-6-R-4,5-dihydro-1,2,4-triazines with arylsulfonylacetonitriles and with dinitriles of sulfonyldiacetic acid and methylenebis(sulfonylacetic) acid have been studied. 7-Amino-3-R-8-(R'-sulfonyl)-1,4-dihydropyrazolo[5,1-c][1,2,4]triazin-4-ones have been synthesized and these are the first representatives of geminal sulfones in which the heterocyclic ring is bound directly to the sulfur atoms of the sulfonyl groups.
Keywords:4-amino-3-methylthio-5-oxo-6-R-4,5-dihydro-1,2,4-triazines  7-amino-3-R-8-(R'-sulfonyl)-1,4-dihydropyrazolo[5,1-c][1,2,4]triazin-4-ones  arylsulfonylacetonitriles  dinitriles of sulfonyldiacetic and methylenebis(sulfonylacetic) acids
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