| 4-乙酰氨基-4’-甲基丙烯酰氨基-二苯基甲烷的合成及其聚合 |
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| 引用本文： | 丘坤元,鲁志华.4-乙酰氨基-4’-甲基丙烯酰氨基-二苯基甲烷的合成及其聚合[J].高分子学报,1991(6). |
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| 作者姓名： | 丘坤元 鲁志华 |
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| 作者单位： | 北京大学化学系，北京大学化学系 北京 1000871，北京 1000871 |
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| 摘 要： | N-芳基丙烯酰胺是-类功能性单体,它能与丙烯酸酯类单体进行自由基共聚合。本文以4,4'-二氨基二苯基甲烷为起始原料,合成了新的带有较长侧基的甲基丙烯酰胺类单体,即4-乙酰氨基-4'-甲基丙烯酰氨基-二苯基甲烷(AMDPM)。它能进行自由基聚合或与丙烯酸甲酯(MA)共聚合。
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| 关 键 词： | 4-乙酰氨基-4’-甲基丙烯酰氨基-二苯基甲烷 自由基共聚合 |
SYNTHESIS OF 4-ACETAMINO-4'-METHACRYLOYLAMINO-DIPHENYLMETHANE AND ITS POLYMERIZATION |
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| QIU Kunyuan and LU Zhihua.SYNTHESIS OF 4-ACETAMINO-4''''-METHACRYLOYLAMINO-DIPHENYLMETHANE AND ITS POLYMERIZATION[J].Acta Polymerica Sinica,1991(6). |
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| Authors: | QIU Kunyuan and LU Zhihua |
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| Abstract: | 4-Acetamino-4'-methacryloylaminodiphenylmethane (AMDPM) monomer was synthesized from 4,4'-diaminodiphenylmethane via acetylation reaction and then reacted with methacryloyl chloride. AMDPM monomer was characterized by elemental analysis,1H-NMR and IR spectra. In the presence of 2,2'-azobisisobutyronitrile (AIBN) AMDPM polymerized and formed a brittle homopolymer. The copolymers of methyl acrylate(MA) with AMDPM in various molar ratio were synthesized via free radical polymerization in N,N-dimethylformamide solution. The monomer reactivity ratios were determined by Fineman-Ross method. |
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| Keywords: | 4-Acetamino-4'-methacryloylamino-diphenylmethane monomer Synthesis Radical polymerization Copolymerization |
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