| 硅丙乳液的合成工艺研究 |
| |
| 引用本文： | 裴世红,秦栋,庄超,王丽丽,陶洋.硅丙乳液的合成工艺研究[J].化学研究与应用,2011,23(10):1413-1417. |
| |
| 作者姓名： | 裴世红 秦栋 庄超 王丽丽 陶洋 |
| |
| 作者单位： | 1. 沈阳化工大学,辽宁沈阳110142;中化二建集团有限公司,山西太原030021
2. 沈阳化工大学,辽宁沈阳,110142 |
| |
| 基金项目： | 辽宁省教育厅创新团队基金项目(LT2010086) |
| |
| 摘 要： | 采用半连续种子乳液聚合工艺,以乙烯基三乙氧基硅烷(VTS)为改性剂、十二烷基硫酸钠(SDS)和烷基酚聚氧乙烯醚(OP-1O)为复合乳化体系,在引发剂过硫酸铵(APS)的作用下合成稳定的硅丙乳液.利用红外光谱(FTIR)和扫描电镜(SEM)对涂膜进行了表征.结果表明:单体转化率随乳化剂用量、引发剂用量、有机硅用量、聚合温...
|
| 关 键 词： | 种子乳液聚合 有机硅 丙烯酸酯 FTIR |
The synthesis process of silicon a crylic-acid emulsion |
| |
| PEI Shi-hong,QIN Dong,ZHUNG Chao,WANG Li-li,TAO Yang.The synthesis process of silicon a crylic-acid emulsion[J].Chemical Research and Application,2011,23(10):1413-1417. |
| |
| Authors: | PEI Shi-hong QIN Dong ZHUNG Chao WANG Li-li TAO Yang |
| |
| Institution: | PEI Shi-hong1,QIN Dong2,ZHUNG Chao1,WANG Li-li1,TAO Yang1(1.Shenyang University of Chemical Technology,Liaoning University,110142,China,2.China Chemical Engineering Second Construction Corporation,Shanxi University,030021,China) |
| |
| Abstract: | A silicone acrylate emulsion is prepared by semicontinuous emulsion polymerization techniques,and take vinyl triethoxy silane(VES)as modifier,sodium dodecyl sulfate(SDS)and alkylphenol ethoxylates(OP-10)as emulsification system and ammonium persulfate as initiator.The coated membrane is analyzed by infrared spectroscopy(FTIR)and scanning electron microscopy(SEM).The results shows that the monomer conversion fisrtly increases and then decreases when the amount of emulsifier,initiator,silicone,the temperature... |
| |
| Keywords: | seeded emulsion polymerization silicone acrylate FTIR |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
