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SBA‐15‐Oxynitrides as a Solid‐Base Catalyst: Effect of Nitridation Temperature on Catalytic Activity
Authors:Baljeet Singh  Dr Kaustubh R Mote  Dr C S Gopinath  Prof Dr P K Madhu  Prof Dr Vivek Polshettiwar
Institution:1. Department of Chemical Sciences, Tata Institute of Fundamental Research (TIFR), Mumbai (India);2. TIFR Centre for Interdisciplinary Sciences, Hyderabad (India);3. National Chemical Laboratory (NCL), Pune (India)
Abstract:Solid bases, such as SBA‐15‐oxynitrides, have attracted considerable interest for potential applications as catalysts in important industrial processes. Reported herein is that by simply tuning the temperature of nitridation (ammonolysis), the catalytic activity of these solid bases can be enhanced. Solid‐state NMR spectroscopy and XPS studies provided the reasoning behind this change in activity.
Keywords:heterogeneous catalysis  nanostructures  NMR spectroscopy  photoelectron spectroscopy  solid‐state structures
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