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A Metal‐Free N‐Annulated Thienocyclopentaperylene Dye: Power Conversion Efficiency of 12 % for Dye‐Sensitized Solar Cells
Authors:Zhaoyang Yao  Dr Min Zhang  Dr Renzhi Li  Lin Yang  Yongna Qiao  Prof Peng Wang
Institution:1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 13002 (China);2. University of Chinese Academy of Sciences, Beijing, 100049 (China)
Abstract:Reported are two highly efficient metal‐free perylene dyes featuring N‐annulated thienobenzoperylene (NTBP) and N‐annulated thienocyclopentaperylene (NTCP), which are coplanar polycyclic aromatic hydrocarbons. Without the use of any coadsorbate, the metal‐free organic dye derived from the NTCP segment was used for a dye‐sensitized solar cell which attained a power conversion efficiency of 12 % under an irradiance of 100 mW cm?2, simulated air mass global (AM1.5G) sunlight.
Keywords:cyclic voltammetry  dyes/pigments  energy conversion  polycycles  solar cells
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