Palladium‐Catalyzed Hydrocarboxylation of Alkynes with Formic Acid |
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Authors: | Jing Hou Prof. Jian‐Hua Xie Prof. Qi‐Lin Zhou |
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Affiliation: | State Key Laboratory and Institute of Elemento‐organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cn |
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Abstract: | A palladium‐catalyzed hydrocarboxylation of alkynes with formic acid has been developed. The method provides acrylic acid and derivatives in good yields with high regioselectivity without the need to handle toxic CO gas. |
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Keywords: | alkynes carboxylic acids palladium P ligands synthetic methods |
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