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Nickel‐Catalyzed Enantioselective CC Bond Formation through CO Cleavage in Aryl Esters |
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| Authors: | Josep Cornella Evan P Jackson Prof Ruben Martin |
| Institution: | 1. Institute of Chemical Research of Catalonia (ICIQ), Av. Pa?sos Catalans 16, 43007, Tarragona (Spain);2. Catalan Institution for Research and Advanced Studies (ICREA), Passeig Llu?s Companys, 23, 08010, Barcelona (Spain) |
| Abstract: | We report the first enantioselective C? C bond formation through C? O bond cleavage using aryl ester counterparts. This method is characterized by its wide substrate scope and results in the formation of quaternary stereogenic centers with high yields and asymmetric induction. |
| Keywords: | aryl esters C‐O cleavage C‐O electrophiles nickel catalysis |