Phenanthriporphyrin: An Antiaromatic Aceneporphyrinoid as a Ligand for a Hypervalent Organophosphorus(V) Moiety |
| |
| Authors: | Dr Bartosz Szyszko Dr Agata Białońska Dr Ludmiła Szterenberg Prof Dr Lechosław Latos‐Grażyński |
| |
| Institution: | Department of Chemistry, University of Wroc?aw, 14 F. Joliot‐Curie St., 50‐383 Wroc?aw (Poland) http://llg.chem.uni.wroc.pl |
| |
| Abstract: | The incorporation of a phenanthrene moiety into a porphyrin framework results in the formation of a hybrid macrocycle—phenanthriporphyrin—merging the structural features of polycyclic aromatic hydrocarbons and porphyrins. An antiaromatic aceneporphyrinoid, adopting the trianionic {CCNN} core, is suitable for the incorporation of a phosphorus(V) center to form a hypervalent organophosphorus(V) derivative. |
| |
| Keywords: | antiaromaticity conjugation phenanthrene phosphorus porphyrinoids |
|
