Rhodium(III)‐Catalyzed [3+2]/[5+2] Annulation of 4‐Aryl 1,2,3‐Triazoles with Internal Alkynes through Dual C(sp2)H Functionalization |
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| Authors: | Yuan Yang Ming‐Bo Zhou Xuan‐Hui Ouyang Rui Pi Dr. Ren‐Jie Song Prof. Dr. Jin‐Heng Li |
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| Affiliation: | 1. State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082 (China);2. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000 (China) |
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| Abstract: | A rhodium(III)‐catalyzed [3+2]/[5+2] annulation of 4‐aryl 1‐tosyl‐1,2,3‐triazoles with internal alkynes is presented. This transformation provides straightforward access to indeno[1,7‐cd]azepine architectures through a sequence involving the formation of a rhodium(III) azavinyl carbene, dual C(sp2)? H functionalization, and [3+2]/[5+2] annulation. |
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| Keywords: | alkynes annulation indeno[1,7‐cd]azepines rhodium triazoles |
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