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CO2‐Responsive Nanofibrous Membranes with Switchable Oil/Water Wettability
Authors:Hailong Che  Meng Huo  Liao Peng  Tommy Fang  Na Liu  Prof Lin Feng  Prof Yen Wei  Prof Jinying Yuan
Institution:1. Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing, 100084 (P.R. China);2. Key Lab of Bioorganic Phosphorus Chemistry & Chemical Biology of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing, 100084 (P. R. China)
Abstract:Responsive polymer interfacial materials are ideal candidates for controlling surface wetting behavior. Here we developed smart nanostructured electrospun polymer membranes which are capable of switching oil/water wettability using CO2 as the trigger. In particular, the combination of CO2‐responsiveness and porous nanostructure enables the as‐prepared membranes to be used as a novel oil/water on–off switch. We anticipate that the promising versatility and simplicity of this system would not only open up a new way of surface wettability change regulation by gas, but also have obvious advantages in terms of highly controlled oil/water separation and CO2 applications.
Keywords:carbon dioxide  electrospinning  oil/water separation  stimuli‐responsive materials  surface chemistry
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