Redox‐Active NOx Ligands in Palladium‐Mediated Processes |
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Authors: | Prof. Ian J. S. Fairlamb |
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Affiliation: | Organic and Inorganic Chemistry, University of York, Chemistry, Heslington, York, YO10 5DD (UK) |
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Abstract: | This Minireview highlights the redox and non‐innocent behavior of NOx ligands (x=1, 2, or 3) in selected Pd‐mediated processes, for example, alkene and aromatic oxidation processes. A focus is placed on mechanistic understanding and linking recent transformations, such as C? H bond activation/functionalization and Wacker oxidation, with previous work on the functionalization of aromatics and alkenes by PdII salts. |
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Keywords: | C C coupling oxidation palladium reaction mechanisms redox reactions |
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