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Hybrid Fibers Made of Molybdenum Disulfide,Reduced Graphene Oxide,and Multi‐Walled Carbon Nanotubes for Solid‐State,Flexible, Asymmetric Supercapacitors
Authors:Dr. Gengzhi Sun  Xiao Zhang  Rongzhou Lin  Jian Yang  Prof. Hua Zhang  Prof. Peng Chen
Affiliation:1. School of Chemical and Biomedical Engineering, Nanyang Technological University, 70 Nanyang Drive, Singapore 637457 (Singapore);2. School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore) http://www.ntu.edu.sg/home/hzhang/;3. School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)
Abstract:One of challenges existing in fiber‐based supercapacitors is how to achieve high energy density without compromising their rate stability. Owing to their unique physical, electronic, and electrochemical properties, two‐dimensional (2D) nanomaterials, e.g., molybdenum disulfide (MoS2) and graphene, have attracted increasing research interest and been utilized as electrode materials in energy‐related applications. Herein, by incorporating MoS2 and reduced graphene oxide (rGO) nanosheets into a well‐aligned multi‐walled carbon nanotube (MWCNT) sheet followed by twisting, MoS2‐rGO/MWCNT and rGO/MWCNT fibers are fabricated, which can be used as the anode and cathode, respectively, for solid‐state, flexible, asymmetric supercapacitors. This fiber‐based asymmetric supercapacitor can operate in a wide potential window of 1.4 V with high Coulombic efficiency, good rate and cycling stability, and improved energy density.
Keywords:carbon nanotubes  flexible devices  graphene  molybdenum disulfide  supercapacitors
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