| A New 3D Supramolecular Network Formed by [Zn_3（2,6-Pyridinedicarboxylate）_3Cl_4]~（4-）and 4-Carboxypyridinium |
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| 引用本文： | YANG E,KANG Yao,WANG Xiao-Qin,LIU Zi-Sheng,LI Jun-Qian. A New 3D Supramolecular Network Formed by [Zn_3（2,6-Pyridinedicarboxylate）_3Cl_4]~（4-）and 4-Carboxypyridinium[J]. 结构化学, 2010, 29(5): 774-778 |
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| 作者姓名： | YANG E KANG Yao WANG Xiao-Qin LIU Zi-Sheng LI Jun-Qian |
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| 作者单位： | YANG E(Department of Chemistry,Fuzhou University,Fuzhou 350002,China ;Fujian Key Lab Polymer Material,College of Chemistry & Materials Science,Fujian Normal University,Fuzhou 350007,China);KANG Yao,WANG Xiao-Qin(Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China);LIU Zi-Sheng(Fujian Key Lab Polymer Material,College of Chemistry & Materials Science,Fujian Normal University,Fuzhou 350007,China);LI Jun-Qian(Department of Chemistry,Fuzhou University,Fuzhou 350002,China ;Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China) |
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| 基金项目： | This work was supported by the Natural Science Foundation of Fujian Province （2006F3042） |
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| 摘 要： | A new compound [Zn3(C7NO4H3)3Cl4]·[C6NO2H6]4·4H2O (I) has been synthesized and structurally characterized by X-ray crystallography.It crystallizes in monoclinic,space group C2/c with a=16.9018(14),b=12.6902(10),c=25.1170(2),β=90.54°,V=5387.0(8)3,Z=4,Zn3C45H41Cl4N7O24,Mr=1401.76,Dc=1.728 g/cm3,F(000)=2840,μ(MoKa)=1.615 mm-1,the R= 0.0758 and wR=0.2060 for 3468 observed reflections (I 2σ(I)).Analysis of single-crystal X-ray diffraction data shows that compound I displays an interesting example of 3D supramolecular networks with perfect neutral and ionic hydrogen bonding array.
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| 关 键 词： | 三维网 吡啶基 单晶X射线衍射 羧基 特征X射线 单斜晶系 数据分析 氢键网络 |
A New 3D Supramolecular Network Formed by [Zn3(2,6-Pyridinedicarboxylate)3Cl4]4- and 4-Carboxypyridinium |
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| YANG E,KANG Yao,WANG Xiao-Qin,LIU Zi-Sheng,LI Jun-Qian. A New 3D Supramolecular Network Formed by [Zn3(2,6-Pyridinedicarboxylate)3Cl4]4- and 4-Carboxypyridinium[J]. Chinese Journal of Structural Chemistry, 2010, 29(5): 774-778 |
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| Authors: | YANG E KANG Yao WANG Xiao-Qin LIU Zi-Sheng LI Jun-Qian |
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| Abstract: | A new compound [Zn3(C7NO4H3)3Cl4]·[C6NO2H6]4·4H2O (Ⅰ) has been synthesized and structurally characterized by X-ray crystallography. It crystallizes in monoclinic, space group C2/c with a = 16.9018(14), b = 12.6902(10), c = 25.1170(2) (A), β = 90.54°, V= 5387.0(8) (A)3, Z = 4,Zn3C45H41Cl4N7O24, Mr = 1401.76, Dc = 1.728 g/cm3, F(000) = 2840,μ(MoKα) = 1.615 mm-1, the R =0.0758 and wR = 0.2060 for 3468 observed reflections (Ⅰ＞ 2σ(Ⅰ)). Analysis of single-crystal X-ray diffraction data shows that compound Ⅰ displays an interesting example of 3D supramolecular networks with perfect neutral and ionic hydrogen bonding array. |
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| Keywords: | crystal structure 3D supramoleeular network hydrogen bonding array |
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