Solvothermal Synthesis,Crystal Structure and Optical Property of Lanthanide Selenidostannate [{Tb(en)_3}_2(μ-OH)_2]Sn_2Se_6 with a 3-D H-bonded Network |
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作者姓名: | CHEN Jiang-Fang LIANG Jing-Jing ZHAO Jing JINAG Wen-Qing ZHANG Yong JIA Ding-Xian |
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作者单位: | College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China |
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基金项目: | Supported by the National Natural Science Foundation of China (No. 20771077) |
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摘 要: | An inorganic-organic hybrid lanthanide selenidostannate {Tb(en)3}2(μ-OH)2]Sn2Se6(1) was synthesized by the solvothermal method.1 crystallizes in the monoclinic system,space group P21/n with a=10.120(2),b=11.781(3),c=15.403(3),β=99.534(5)°,V=1811.1(7)3,Mr=1423.62,Z=2,Dc=2.611 g/cm3,μ=11.281 mm-1,F(000)=1312,S=1.101,the final R= 0.0400 and wR=0.0853 for 3242 observed reflections with Ⅰ> 2σ(Ⅰ).1 consists of a Sn2Se6]4-and a {Tb(en)3}2(μ-OH)2]4+ ions.The Sn2Se6]4-anion is constructed by two SnSe4 tetrahedra sharing a common edge.The binuclear {Tb(en)3}2(μ-OH)2]4+ complex is composed of two Tb(en)3]3+ ions joined by two μ-OH bridging ligands.The Tb3+ ion lies in an eight-coordinated bicapped trigonal prism.In 1,the Sn2Se6]4-and {Tb(en)3}2(μ-OH)2]4+ moieties are connected into a 3-D network via N-H···Se and O-H···Se H-bonds.
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关 键 词: | 溶剂热合成 晶体结构 混合稀土 网络连接 光学性质 H型 铽离子 负离子 |
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