Three-dimensional ordering of impurity-doped TMMC in a magnetic field

The three-dimensional ordering temperatures of the quasi-one-dimensional antiferromagnet (CH₃)₄NMnCl₃ containing 0, 0.13, 0.25 and 0.48 at% Cu²⁺ ions were studied as a function of an external magnetic field up to 60 kOe by means of proton NMR. A strong increase of T_N(H) with H was found even for the impure system. The T_N versus H curve for the pure system cam be explained by introducing a simple form for the effect of the field on the correlation length, ξ(T, H) = ξ(T) × 1+(λJ/kT)H²], while that for the impure system is unlike the one for the pure system.