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多相固体催化剂用于甘油氧化制乳酸研究进展
引用本文:唐成,李双明,于三三. 多相固体催化剂用于甘油氧化制乳酸研究进展[J]. 分子催化, 2022, 36(4): 398-412
作者姓名:唐成  李双明  于三三
作者单位:沈阳化工大学 化学工程学院, 辽宁 沈阳 110142,沈阳化工大学 化学工程学院, 辽宁 沈阳 110142;辽宁省化工分离技术重点实验室, 辽宁 沈阳 110142,沈阳化工大学 化学工程学院, 辽宁 沈阳 110142;辽宁省化工分离技术重点实验室, 辽宁 沈阳 110142
基金项目:辽宁省“兴辽英才计划”科技创新领军人才项目(XLYC2002001); 辽宁省自然科学基金面上项目(2021-MS-255); 沈阳市中青年科技创新人才支持计划(RC210184)
摘    要:
随着新的全球气候协议下的中国双碳行动计划的实施, 开发和利用可再生生物质资源显得极为重要. 甘油作为生物柴油在生产过程中的主要副产物, 将其催化转化成各种高附加值衍生物受到广泛关注, 其中甘油选择性氧化为乳酸具有巨大的应用前景. 近年来, 采用固体催化剂催化氧化甘油制乳酸成为国内外学者研究的热点. 我们综述了固体催化剂用于甘油催化转化制备乳酸的研究现状, 对甘油催化转化为乳酸的反应途径做了分析, 并讨论了影响催化剂活性的因素, 对当前所存在的问题提出建议, 也对未来相关催化剂制备发展进行了展望.

关 键 词:固体催化剂  甘油  乳酸  碳中和  氧化反应
收稿时间:2022-04-28
修稿时间:2022-06-10

Advances in Heterogeneous Solid Catalysts for Oxidation of Glycerol to Lactic Acid
Tang Cheng,Li Shuang-ming and Yu San-san. Advances in Heterogeneous Solid Catalysts for Oxidation of Glycerol to Lactic Acid[J]. Journal of Molecular Catalysis (China), 2022, 36(4): 398-412
Authors:Tang Cheng  Li Shuang-ming  Yu San-san
Affiliation:College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China,College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China;Key Laboratory of Chemical Separation Technology of Liaoning Province, Shenyang 110142, China and College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China;Key Laboratory of Chemical Separation Technology of Liaoning Province, Shenyang 110142, China
Abstract:
With the implementation of China''s dual carbon action plan under the new global climate agreement, it is extremely important to develop and utilize renewable biomass resources. As the main by-product of biodiesel in the production process, catalytic conversion of glycerol into various high value-added derivatives has received wide attention, among which selective oxidation of glycerol to lactic acid has great application prospects. In recent years, the catalytic oxidation of glycerol to lactic acid using solid catalysts has become a hot research topic for scholars at home and abroad. In this paper, the research status of solid catalysts for the catalytic conversion of glycerol to lactic acid is reviewed, the reaction pathway of catalytic conversion of glycerol to lactic acid is analyzed, and the factors affecting the catalyst activity are discussed. The development of related catalyst preparation is prospected.
Keywords:solid catalyst  glycerol  lactic acid  carbon neutral  oxidation reaction
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