Reduction of disulfides in the milligram range with hypophosphorous acid and organic phosphites |
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| Authors: | RE HumphreyCL Oleson GM MatulaAC Vaught |
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| Institution: | Department of Chemistry, Sam Houston State University, Huntsville, Texas 77340 U.S.A. |
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| Abstract: | A number of organic disulfides in the milligram range were reduced to the corresponding thiol by reaction with hypophosphorous acid at elevated temperatures in aqueous solvents. Reduction is extensive after several hours. Aromatic disulfides were reduced by triethyl phosphite and triphenyl phosphite at room temperature. Products were deterimned by polarographic and amperometric titration techniques. |
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