Phase relations of NH4ClO4 and NH4BF4 to high pressures |
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| Authors: | PW RichterCarl WFT Pistorius |
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| Institution: | Chemical Physics Group of the National Physical and National Chemical Research Laboratories, South African Council for Scientific and Industrial Research, Pretoria, South Africa |
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| Abstract: | The high pressure phase diagrams of NH4ClO4 and NH4BF4 were studied by means of differential thermal analysis and volumetric techniques. The high temperature portions of these diagrams are intermediate between those of the corresponding potassium and rubidium salts, but at low temperatures the onset of hydrogen bonding causes the appearance of phases which are unique to the ammonium compounds. |
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