An efficient oxidation of benzylic and alicylic compounds with water-soluble copper catalysts in t-butyl hydroperoxide at room temperature |
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| Authors: | Ateeq Rahman SMAl Zahrania Abdel Aziz Nait Ajjoub a College of Engineering |
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| Institution: | a College of Engineering, Department of Chemical Engineering, King Saud University, Riaydh-11421, Saudi Arabia;b Department of Chemistry and Biochemistry, University of Moncton, Moncton, New Brunswick, E1A3E9, Canada |
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| Abstract: | The water soluble catalytic system comprising of CuCl_2 and 2,2-biquinoline-4,4-dicarboxylic acid dipotassium salt(BQC) is highly efficient organic metallic catalysts for selective oxidation of benzyiic and alicyciic compounds to the corresponding ketones, ex:indan to indanone,ethyl benzene to acetophenone. |
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| Keywords: | Oxidation Bibenzyl Allyl benzene Indan 2-Biquinoline-4 4-dicarboxylic acid dipotassium salt(BQC) Tetrabutyl ammonium bromide(TBAC) |
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