Formation of non-racemic E- and Z-olefins based on discrimination of enantiotopic carbonyl groups in α-diketones by a chiral phosphonate reagent |
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| Authors: | Kiyoshi Tanaka Toshiyuki Watanabe Yoshihisa Ohta Kaoru Fuji |
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| Affiliation: | Institute for Chemical Research, Kyoto University, Uji, Kyoto 611, Japan |
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| Abstract: | A chiral HWE reagent reacted with an alternative carbonyl group of meso-α-diketones of bicyclo[2.2.1] system to give non-racemic (Z)- and (E)-olefins, respectively. |
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