Electronic state of the active site of A V?P?O/SiO<sub>2</sub> catalyst in oxidation of chlorine-containing hydrocarbons期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Electronic state of the active site of A V?P?O/SiO₂ catalyst in oxidation of chlorine-containing hydrocarbons

Authors:	A G Agazade G A Dergaleva V F Anufrienko A A Davydov T N Shakhtakhtinskii and A D Efendiev

Institution:	(1) Institute of Catalysis, 630090 Novosibirsk, USSR;(2) Institute of Theoretical Problems of Chemical Technology, Baku, USSR

Abstract:	V⁴⁺ ions in slightly associated states are supposed to play the role of V–P–O/SiO₂ active sites. V⁴⁺ ions are reduced to V³⁺ during deactivation of the V–P–O/SiO₂ catalyst. V–P–O/SiO₂ V⁴⁺ . V–P–O/SiO₂ V⁴⁺ V³⁺.

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