Novel chiral calix[4]arenes by direct asymmetric epoxidation reaction |
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| Authors: | Bonini Carlo Chiummiento Lucia Funicello Maria Lopardo Maria Teresa Lupattelli Paolo Laurita Alessandro Cornia Andrea |
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| Affiliation: | Dipartimento di Chimica, Università degli studi della Basilicata, via Nazario Sauro 85, Potenza, Italy. bonini@unibas.it |
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| Abstract: | We report the first asymmetric synthesis of trans optically active (+) C 2 1,3-bisarylepoxide of calix[4]arene in excellent chemical yield and >99% ee, and its enantiospecific conversion to the corresponding bis-dioxolane. |
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