Syntheses of highly fluorinated 1,3,5-triazapentadienyl ligands and their use in the isolation of copper(I)-carbonyl and copper(I)-ethylene complexes |
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| Authors: | Dias H V Rasika Singh Shreeyukta Flores Jaime A |
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| Affiliation: | Department of Chemistry and Biochemistry, University of Texas at Arlington, Arlington, Texas 76019, USA. dias@uta.edu |
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| Abstract: | Fully fluorinated triazapentadienyl ligand [N{(C3F7)C(C6F5)N}2]- and the related [N{(C3F7)C(2-F,6-(CF3)C6H3)N}2]- have been synthesized in good yield via a convenient route and used in the isolation of three- and four-coordinate copper(I)-carbon monoxide complexes. They show fairly high nu(CO) values (>2100 cm(-1)), indicating the presence of electron-poor Cu sites. The copper(I)-ethylene adduct [N{(C3F7)C(C6F5)N}2]Cu(C2H4), featuring a three-coordinate Cu site, has also been synthesized using [N{(C3F7)C(C6F5)N}2]CuNCCH3 and C2H4. |
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