Complexation of Titanium n-butoxide Ti(OBu n )4 and Zirconium n-butoxide Zr(OBu n )4 with Some Oxime Ligands and Structural Analysis of the Complexes |
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Authors: | Birsen S. Buyuktas Ozgur Aktas |
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Affiliation: | (1) Department of Chemistry, Akdeniz University, 07058 Antalya, Turkey |
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Abstract: | Titanium tetra-n-butoxide, Ti(OBun)4, and zirconium tetra-n-butoxide, Zr(OBun)4, were reacted with some well-known dioxime and monoxime ligands such as dimethylglyoxime (DMG), salicylaldoxime (SO) and acetone oxime (AO). The structures of the resulting complexes have been determined by elemental analysis, i.r. and 1H-n.m.r. spectroscopy. The complexation ratio of both Ti(OBun)4 and Zr(OBun)4 was found to be 1:2 with DMG and SO. On the other hand, both 1:1 and 1:2 complexation ratios of the same metal alkoxides were observed with the ligand AO. |
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