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A theoretical study of coherence transfer by isotropic mixing
Authors:M Lyndsay Remerowski  Steffen J Glaser  Gary P Drobny
Institution:Department of Chemistry , University of Washington , Seattle, Washington, 98195, U.S.A.
Abstract:Computer simulations of coherence transfer functions under the isotropic mixing hamiltonian are presented for amino acids and the deoxyribose moiety in DNA. They allow the determination of the optimum mixing time in a two-dimensional TOCSY experiment. The effects of experimental parameters and pulse imperfections are discussed for practical pulse sequences.
Keywords:
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