Partial chlorine-chlorine intermolecular scattering functions for XCl4 liquids (X = C,Si, Ge,V, Ti,Sn) from neutron diffraction and the RISM |
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| Authors: | Jan B van Tricht Jelle S Sjoerdsma |
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| Institution: | 1. Interuniversitair Reactor Instituut , Mekelweg 15, 2629 JB, Delft, The Netherlands;2. Interuniversitair Reactor Instituut , Mekelweg 15, 2629 JB, Delft, The Netherlands;3. Automation Centre ‘VOLMAC’ , Postbox 2575, 3500GN, Utrecht, The Netherlands |
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| Abstract: | Combining neutron diffraction intermolecular scattering functions with RISM partial scattering function for X-X and X-Cl atom paris the Cl-Cl partial scattering functions are obtained. The systematic trends in Cl-Cl partial scattering functions and radial distribution functions in six different tetrachloride liquids have been investigated. The intermolecular nearest neighbour Cl-Cl distance of 0·377(14) nm corresponds well with the value of 0·34 nm adopted for the chlorine hard sphere diameter in the RISM calculations. |
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