Electric field dissociation of H+ 2: close-coupled scattering calculations |
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| Authors: | CHRISTINE A. LEACH M. S. CHILD D. E. MANOLOPOULOS |
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| Affiliation: | 1. Department of Chemistry , University of Southampton , Southampton , SO17 1BJ , UK;2. Physical and Theoretical Chemistry Department , Oxford University , South Parks Road , Oxford , OX1 3QZ , UK |
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| Abstract: | Close-coupling scattering calculations have been carried out to predict the magnitude of electric fields required to dissociate specific vibration—rotation levels in H+ 2. Results for electric fields up to 40 kV cm?1, which may dissociate levels up to 25 cm?1 below the dissociation limit, are presented. The results are used to simulate spectra which are compared with experimental spectra. A method for extracting the eigenphase sum from a coupled channel scattering calculation is described in the appendix and used in the calculations. |
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