Solvent-free methylthiomethyllithium [LiCH2SMe]infinity: solid state structure and thermal decomposition |
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| Authors: | Ruth Kai Dinnebier Robert E Tönnes Stefan W Alig Edith Sänger Ingeborg Lerner Hans-Wolfram Wagner Matthias |
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| Institution: | Institut für Anorganische Chemie, J.W. Goethe-Universit?t Frankfurt, Marie-Curie-Strasse 11, D-60439, Frankfurt (Main), Germany. |
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| Abstract: | Solvent-free LiCH2SMe]infinity forms a layer structure consisting of four- (Li2C2), five- (Li2CS2), and six-membered (Li2C2S2) rings in the solid state; the compound violently explodes upon heating to T=160+/-5 degrees C under an argon atmosphere. |
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