| 漆酚铝螯合聚合物的合成研究 |
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| 引用本文： | 胡炳环,林金火. 漆酚铝螯合聚合物的合成研究[J]. 高分子学报, 1991, 0(3): 286-292 |
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| 作者姓名： | 胡炳环 林金火 |
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| 作者单位： | 福建师范大学高分子研究所，福建师范大学高分子研究所 福州 350007，福州 350007 |
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| 摘 要： | 本文报道漆酚与无水氯化铝反应合成漆酚铝螯合物的方法,并通过测定反应过程HCl析出量、产物含铝量,并用红外光谱、质谱,研究其结构特征。实验表明,部分螯合的漆酚铝螯合型高聚物涂料,具有优良的物理机械性能和优异的耐热性能。
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| 关 键 词： | 漆酚 漆酚铝螯合物 无水氯化铝 单元结构 热稳定性 |
| 收稿时间： | 1989-12-02 |
SYNTHESIS OF URUSHIOL-ALUMINIUM CHELATE POLYMERS |
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| HU Bing-huan,LIN Jin-huo. SYNTHESIS OF URUSHIOL-ALUMINIUM CHELATE POLYMERS[J]. Acta Polymerica Sinica, 1991, 0(3): 286-292 |
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| Authors: | HU Bing-huan LIN Jin-huo |
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| Affiliation: | Institute of Polymer Science; Fujian Teachers University; Fuzhou; Post code 350007 |
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| Abstract: | Urushiol-aluminium chelate polymers were synthesized by reaction of urushiol and aluminium chloride. Polymers with different aluminium content were obtained through different urushiol-AlCl3 molar ratios. IR spectra showed that new peaks appeared at 580-660 cm-1, and peake at 3200-3500 cm-1 greatly weakened, We can conclude new compound was formed after, reaction. The weakness and disappearance of double bond absorption indicated the urush-iol-aluminium chelate converted to polymer during reaction. MS results showed urushiol and AlCls formed chelate compound initially. Coatings made from these chelate polymers possessing excellent physico-mechanical properties and good heat-stability. |
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| Keywords: | Urushiol Urushiol-alumiuium chelate Aluminium chloride Unit structure Heat-stability |
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