| 含非交换氘的四唑-锌配合物 |
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| 引用本文： | 王国喜,李 波,熊仁根. 含非交换氘的四唑-锌配合物[J]. 无机化学学报, 2007, 23(11): 1997-1998 |
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| 作者姓名： | 王国喜 李 波 熊仁根 |
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| 作者单位： | 南京大学配位化学研究所,南京,210093 |
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| 摘 要： | The solvothermal reaction (D2O) of 2,6-dideuterium-4-cyanopyridine with ZnCl2 in the presence of NaN3 offers a novel complex Zn(OD)(C6H2D2N4) (1) in which Zn has a distorted tetrahedron composed of two N atoms from one tetrazoyl group and pyridyl group and two O atoms from two deuteratohydroxy OD groups. Crystal data for 1: Pbcn, a=1.456 8(5) nm, b=0.659 2(2) nm, c=1.645 3(5) nm, α=90°, β=90°, γ=90°, V=1.580 0(9) nm3, Z=8, M=231.54, Dc=2.236 Mg·m-3, μ=3.070 mm-1, R1=0.043 4, wR2=0.120 6, S=1.029. CCDC: 660629.
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| 关 键 词： | 氘； 锌(Ⅱ)配合物； 溶剂热合成； 晶体结构 |
| 文章编号： | 1001-4861（2007）11-1997-02 |
| 修稿时间： | 2007-09-29 |
First Crystallographically Characterized Zinc Tetrazole Complex with Partial Non-exchange Deuterium |
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| WANG Guo-Xi,LI Bo and XIONG Ren-Gen. First Crystallographically Characterized Zinc Tetrazole Complex with Partial Non-exchange Deuterium[J]. Chinese Journal of Inorganic Chemistry, 2007, 23(11): 1997-1998 |
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| Authors: | WANG Guo-Xi LI Bo XIONG Ren-Gen |
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| Affiliation: | Coordination Chemistry Institute, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, Nanjing University, Nanjing 210093 and Coordination Chemistry Institute, Nanjing University, Nanjing 210093 |
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| Abstract: | The solvothermal reaction (D2O) of 2,6-dideuterium-4-cyanopyridine with ZnCl2 in the presence of NaN3 offers a novel complex Zn(OD)(C6H2D2N4) (1) in which Zn has a distorted tetrahedron composed of two N atoms from one tetrazoyl group and pyridyl group and two O atoms from two deuteratohydroxy OD groups. Crystal data for 1: Pbcn, a=1.456 8(5) nm, b=0.659 2(2) nm, c=1.645 3(5) nm, α=90°,β=90°, γ=90°, V=1.580 0(9) nm3,Z=8, M=231.54, Dc=2.236 Mg·m-3,μ=3.070 mm-1, R1=0.043 4, wR2=0.120 6, S=1.029. CCDC: 660629. |
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| Keywords: | deuterium solvothermal reaction crystal structure |
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